If you have full pgadmin3 you'll get very nice table statistics, but if all you have is psql, matter is more complicated.
You'll need to execute this SQL:
SELECT
table_name,
pg_size_pretty(table_size) AS table_size,
pg_size_pretty(indexes_size) AS indexes_size,
pg_size_pretty(total_size) AS total_size
FROM (
SELECT
table_name,
pg_table_size(table_name) AS table_size,
pg_indexes_size(table_name) AS indexes_size,
pg_total_relation_size(table_name) AS total_size
FROM (
SELECT ('"' || table_schema || '"."' || table_name || '"') AS table_name
FROM information_schema.tables
) AS all_tables
ORDER BY total_size DESC
) AS pretty_sizes